Hybrid Energy Systems Which Include Waste Heat Recovery and Conversion

Waste heat losses arise both from equipment inefficiencies and from thermodynamic limitations on equipment and processes. For example, consider reverberatory furnaces frequently used in aluminum melting operations. Exhaust gases immediately leaving the furnace can have temperatures as high as 2,200°F-2,400°F [1,200°C-1,300°C]. Consequently, these gases have high heat content, carrying away as much as 60% of furnace energy inputs. Efforts can be made to design more energy-efficient reverberatory furnaces with better heat transfer and lower exhaust temperatures; however, the laws of thermodynamics place a lower limit on the temperature of exhaust

TABLE 7.3

2010 Production, Calculated Onsite Energy Consumption, and Energy Savings Potential for Eleven Chemicals [1]

Chemical

Annual Production (Million Ibs/y)

Calculated Onsite Energy (TBtu/y)

Energy Reduction Opportunity (TBtu/y)

Ethanol

66.100

307

264

Ethylene

52.900

374

107

Ammonia

22.700

133

78

Benzene

13.300

104

67

Chlorine/sodium hydroxide

21.500/16.600

203

87

Nitrogen/oxygen

69.600/58.300

99

18

Ethylene dichloride

19.400

66

37

Propylene

31.100

42

11

Acetone

3.180

25

18

Ethylene oxide

5.880

11

4

Methanol

2.020

10

4

Total

382.000

1.370

695

gases. Since heat exchange involves energy transfer from a high-temperature source to a low-temperature sink, the combustion gas temperature must always exceed the molten aluminum temperature in order to facilitate aluminum melting. The gas temperature in the furnace will never decrease below the temperature of the molten aluminum, since this would violate the second law of thermodynamics. Therefore, the minimum possible temperature of combustion gases immediately exiting an aluminum reverberatory furnace corresponds to the aluminum pouring point temperature 1,200°F-1,380°F [650°C-750°C]. In this scenario, at least 40% of the energy input to the furnace is still lost as waste heat. Many examples of industrial waste heat and their possible uses are illustrated in Table 7.4. The Temperature Classification of Waste Heat Sources and Related Recovery Opportunity is illustrated in Table 7.5.

Recovering waste heat requires implementation of hybrid process like cogeneration or CHP. Industrial waste heat can be recovered via numerous methods. The heat can either be “reused” within the same process or transferred to another process through process hybridization. Ways of reusing heat locally include using combustion exhaust gases to preheat combustion air or feedwater in industrial boilers. By preheating the feedwater before it enters the boiler, the amount of energy required to heat the water to its final temperature is reduced. Alternately, the heat can be transferred to another process; for example, a heat exchanger could be used to transfer heat from combustion exhaust gases to hot air needed for a drying oven. In this manner, the recovered heat can replace fossil energy that would have otherwise been used in the oven. Such methods for recovering waste heat can help facilities significantly reduce their fossil fuel consumption, as well as reduce associated operating costs and pollutant emissions. As shown below, waste heat can also be converted to power by thermoelectric generator, TPV system, or piezoelectric system. Waste heat (particularly at low temperature) can also be used in heat pump.

TABLE 7.4

Examples of Waste Heat Sources and End Uses [34]

Waste Heat Sources

Uses for Waste Heat

  • • Combustion exhausts:
  • • Glass melting furnace
  • • Cement kiln
  • • Fume incinerator
  • • Aluminum reverberatory furnace boiler
  • • Nuclear reactor:
  • • Various applications of solar energy
  • • Various applications of geothermal energy
  • • Off-gases from internal combustion engine
  • • Process off gases:
  • • Steel electric arc furnace
  • • Aluminum reverberatory furnace
  • • Cooling water from: Furnaces
  • • Air compressors
  • • Internal combustion engines
  • • Conductive, convective, and radiative losses from equipment: Hall-Heroult cellsa
  • • Conductive, convective, and radiative losses from heated products:
  • • Hot cokes
  • • Blast furnace slagsa
  • • Combustion air preheating
  • • Boiler feedwater preheating
  • • Load preheating
  • • Power generation
  • • Steam generation for use in:
  • • Power generation
  • • Mechanical power
  • • Process steam
  • • Space heating
  • • Water preheating
  • • Transfer to liquid or gaseous process streams
  • • Solar fuels
  • • Various applications of nuclear waste heat depending on temperature level
  • • Various applications of solar and geothermal energy depending on the temperature levels

TABLE 7.5

Temperature Classification of Waste Heat Sources and Related Recovery

Opportunity [34]

Temp Range

Example Sources

Temp (°F)

Temp (°C)

Very high > 1.600°F

Electrical refractor)' furnace exhaust

2,900-4,500

1,600-2.700

High> 1,200°F (> 650°C)

Nickel refining furnace

2,500-3.000

1,370-1,650

Steel electric arc furnace

2,500-3.000

1,370-1,650

Basic oxygen furnace

2,200

1,200

Aluminum reverberatory furnace

2,000-2,200

1.100-1,200

Copper refining furnace

1,400-1,500

760-820

Steel heating furnace

1,700-1,900

930-1.040

Copper reverberatory furnace

1,650-2.000

900-1.090

Hydrogen plants

1,200-1,800

650-980

Fume incinerators

1,200-2,600

650-1.430

Glass melting furnace

2,400-2,800

1.300-1.540

Coke oven

1,200-1,800

650-1,000

(Continued)

TABLE 7.5 (Continued)

Temperature Classification of Waste Heat Sources and Related Recovery Opportunity [34]

Temp Range

Example Sources

Temp (°F)

Temp (°C)

Iron cupola

1,500-1.800

820-980

Medium

  • 450°F-1,200°F
  • (230°C-650°C)

Steam boiler exhaust

450-900

230-480

Gas turbine exhaust

700-1.000

370-540

Reciprocating engine exhaust

600-1.100

320-590

Heat treating furnace

800-1.200

430-650

Drying and baking ovens

450-1.100

230-590

Cement kiln

840-1.150

450-620

Low <450°F (< 230°C)

Exhaust gases exiting recovery devices in gas fired boilers, ethylene furnaces, etc.

150-450

70-230

Process steam condensate

130-190

50-90

Cooling water from: Furnace doors

90-130

30-50

Annealing furnaces

150-450

70-230

Air compressors

80-120

30-50

Internal combustion engines

150-250

70-120

Air-conditioning and refrigeration condensers

90-110

30-40

Drying, baking, and curing ovens

200-450

90-230

Ultralow < 250°F

Hot processed liquids/ solids

90-450

30-230

Kitchen, ventilation, fryer, condenser exhaust

90-130

30-45

Cooling water from power plants

60-140

15-50

Cooling water from air compressor

75-140

25-50

Industrial-scale energy systems integration provides a systems approach to optimize energy use at manufacturing facilities through technologies that can increase energy flexibility and reduce/recover/reuse waste energy, leading to reduced energy intensity, and narrowing the gap between current energy use and practical minimum energy requirements. Any option for waste heat recovery results in the overall system to be hybrid.

 
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